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High transparency and reduced shrinkage

The nanoparticles described in Section Modifying heat and room temperature curing adhesives with nanoparticles can also be used in UV-curing systems. Nanoparticle modified acrylate monomers (Nanocryl® A) or cycloaliphatic epoxy resins (Nanopox® A 610) enable a whole range of material properties to be significantly improved.

Product overview
Improvements to properties

Product overview [back]

Technical data (no specification)

Type Monomer Characterization SiO 2 -content[wt % ] Dyn. viscosity,
25 ° C [mPa·s
]
Nanocryl®
A 370
HEMA Hydroxyethylmethacrylate 50 60
Nanocryl®
A 200
CTFA Trimethylolpropanformalacrylate 50 275
Nanocryl®
A 210
HDDA Hexandioldiacrylate 50 175
Nanocryl®
A 215
TPGDA Tripropylenglycoldiacrylate 50 200
Nanocryl®
A 216
NPGPODA Propox. Neopentylglycoldiacrylate 50 175
Nanocryl®
A 220
TMPTA Trimethylolpropantriacrylate 50 3,300
Nanocryl®
A 223
TMPEOTA Ethox. Trimethylolpropantriacrylate 50 1,000
Nanocryl®
A 225
GPTA Propox. Glycerintriacrylate 50 1,750
Nanocryl®
A 235
PPTTA Alkox. Pentaerythritoltetraacrylate 50 2,500
Nanopox®
A 610
EEC Cycloaliphatic epoxy resin for cationic curing 40 4,000
Nanopox®
A 660
TMPO Reactive diluent for cationic curing systems 50 200
Note: Further Nanocryl® A products and mixtures for special applications are available on request. Please contact our application engineers.

Improvements to properties [back]

The products are highly transparent, low viscous and do not show any sedimentation, i. e. the processability remains essentially unchanged compared to the respective base resin. This way, the respective advantages of organic and inorganic materials can be combined almost perfectly.

Important material properties which can be improved by the use of Nanocryl® A are:

  • No reduction in transparency despite high filler content
  • Reduced cure shrinkage and heat of reaction
  • Reduced thermal expansion and internal stresses
  • Barrier effect against gases, water vapour and solvents
  • Increased weathering resistance and inhibited thermal aging
  • Greatly improved scratch and abrasion resistance
  • Increase in tear resistance, fracture toughness and modulus
  • Improved adhesion on numerous inorganic substrates (e. g. glass, aluminium)
  • Improvement in numerous other desired properties, such as: thermal stability, stain resistance, heat conductivity, dielectric properties

Nanocryl® A products are not only used in UV adhesives, but also in stereolithography, which is increasingly used as a rapid prototyping process. The transparency, combined with the increase in the strength and modulus, is important here.

For further details, please contact our application specialists.

 
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